Product ID:453, ETHION SUPERIOR 70 OIL INSECTICIDE
MSDS Date:12/06/1991
FSC:6840
NIIN:00N033461
MSDS Number: BPQHZ

FMC CORPORATION

1735 MARKET STREET
PHILADELPHIA, PA 19103
US

Emergency Phone: 202-483-7616;800-424-9300(CHEMTREC)

Info Phone: 800-331-3148;716-735-3765

Cage: 70550

FMC CORPORATION CHEMICAL GROUP

PHILADELPHIA, PA 19103-3230 US

Telephone: 716-735-3765

Cage: 70550

OF ATROPINIZATION APPEAR. 2-PAM IS A PHARMACOLOGIC

RTECS: 9999999ZZ

SUBSTITUTE FOR, ATROPINE. DO NOT GIVE

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ACID DERIVATIVES. DIAZEPAM WAS NOT FOUND TO BE

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EDEMA, PATIENT SHLD BE GIVEN SUPP O*2 & TREATED

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MAY OCCUR, & FATAL RELAPSES HAVE BEEN REPORTED AFTER

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PATIENT IS INDICATED FOR AT LEAST 48 HOURS.

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ALL CLOTHING BEFORE REUSE.

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DRUM. TO DECONTAM SPILL AREA/TOOLS/EQUIP, WASH

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COLLECTED.LABEL DRUMS FOR CONTENTS.DISP OF DRUMMED

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BECAUSE REG REQUIREMENTS MAY CHANGE, THE

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CNTNRS WHICH HELD THESE METLS MAY BE CLEANED BY

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PHOSPHORODITHIOIC ACID, S,S'-METHYLENE 0,0,0,0-TETRAETHYL

CAS: 563-12-2

RTECS: TE4550000

OSHA PEL 0.4 MG/M3, S

ACGIH TLV: 0.4 MG/M3, S

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

ISOPROPYL ALCOHOL; (ISOPROPANOL) (SARA III)

CAS: 67-63-0

RTECS: NT8050000

OSHA PEL 400 PPM;500 PPM STEL

ACGIH TLV: 400 PPM;500 PPM STEL

MINERAL OIL (EXPOSURE REGULATED AS 'OIL MIST')

CAS: 8012-95-1

RTECS: PY8030000

OSHA PEL 5 MG/M3

ACGIH TLV: 5 MG/M3

IN STUDIES W/LAB ANIMALS, ETHION DID NOT

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INHIBITION OF PLASMA CHOLINESTERASE WAS OBSERVED IN

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LACK OF GENOTOXICITY HAS BEEN DEMONSTRATED IN TESTS

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WEAKNESS OF THE EXREMITIES. RECOVERY VARIES FROM

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REMAINING. MODERATE IRRIT CAN RSLT FROM PRLNGD CNTCT

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SKIN. ANIMALS EXPOS TO ISOPROPANOL VIA INHAL HAD

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DEGENERATIVE BRAIN CHANGES.

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AN UNCON PERSON. TRANSPORT IMMMED TO MD.

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TOX. ASPIR/VOMIT MAY PRODUCE A SEVERE PNEUMONITIS.

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ENDOTRACHEAL TUBE IN PLACE. THE ACTIVE INGRED IS AN

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ATROPINE SULFATE AT 2-4 MG DOSE INTRAVENOUSLY OR

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LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:ETHION IS A CHOLINESTERASE
ENZYME-INHIBITING PESTICIDE WHOSE EARLY SYMPS INCL HDCH, DIZZINESS,
WEAKNESS, INCOORDINATION, MUSCLE TWITCHING, TREMORS, NAUS,
ABDOMINAL CRAMPS, DIARRHEA & SWEATING. B LURRED/DARK VISION,
CONFUSION, TIGHTNESS IN CHEST, WHEEZING, PRODUCTIVE COUGH &
PULMONARY EDEMA MAY (EFTS OF OVEREX)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: OCCUR. INCONTINENCE, UNCON &
CONVULSIONS INDICATE VERY SEVERE POISONING. SLOW HEARTBEAT,
SALIVATION & TEARING ARE COMMON. RESP DEPRESSION MAY BE FATAL. TOX
PSYCHOSIS CAN OCCUR & LEAD TO MISD IAGNOSIS. ONE INGRED IN THIS
FORMULATION MAY CAUSE A TEMPORARY STINGING PAIN WHEN IN CONTACT
W/EYE. IRRIT OF (SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYE:FLUSH W/PLENTY OF H*2O FOR @ LST 15 MIN. GET MED ATTN.
SKIN:REMOVE CONTAM CLTHG & WASH W/SOAP & H*2O. IF IRRIT PERSISTS,
CALL MD. INHAL:REMOVE TO FRESH AIR. IF BRTHG DIFFICULTY OCCURS,
CALL MD. IN GEST:DRINK 1-2 GLASSES OF H*2O & INDUCEVOMIT BY
TOUCHING BACK OF THROAT W/FINGER/BY GIVING SYRUP OF IPECAC, UNLESS
MD CAN BE SEEN WITHIN 1 HOUR. DO NOT INDUCE VOMIT/GIVE ANYTHING BY
MOUTH TO (ING 11)

Flash Point:90F,32C
Extinguishing Media:FOAM, CO*2/DRY CHEM. SOFT STREAM H*2O ONLY IF NEC.
CONTAIN RUNOFF. CO, CO*2, PHENOLS, SULFUR OXIDES, MERCAPTANS.
Fire Fighting Procedures:ISOLATE FIRE AREA. EVAC DOWNWIND. WEAR
NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . DO NOT BREATHE SMOKE,
GASES/VAPS GENERATED. TRY TO KEEP (SUPP DATA)
Unusual Fire/Explosion Hazard:SLIGHTLY COMBUST. MATLS MAY SUPPORT
COMBUSTION AT ELEVATED TEMPS. SEALED, OVERHEATED CNTNRS MAY PRESENT
AN EXPLOSION HAZ. ETHION MAY DECOMP RAPDILY (SUPP DATA)

Spill Release Procedures:ISOLATE & POST SPILL AREA. WEAR PRESCRIBED
PROT CLTHG & EQUIP. KEEP OUT UNPROT PERSONS & ANIMALS. KEEP MATL
OUT OF STREAMS & SEWERS. DIKE TO CONFINE SPILL, & ASORB W/ABSORB
SUCH AS CLAY, SAND/CAT LITT ER. VACUUM, SHOVEL/PUMP WASTES INTO
APPRVD(ING 22)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE IN A COOL, WELL-VENT DRY PLACE.
DO NOT STORE <0C(32F). AVOID EXCESS HEAT. STORE IN ORIGINAL CNTNRS
ONLY. KEEP OUT OF REACH OF CHILDREN.
Other Precautions:DO NOT CONTAM OTHER PESTICIDES, FERTILIZERS, H*2O,
FOOD OR FEED BY STORAGE OR DISPOSAL. THOROUGHLY WASH THE OUTSIDES
OF GLOVES W/SOAP & WATER PRIOR TO REMOVAL. DO NOT CUT OR WELD METAL
CNTNRS. VAPS TH AT FORM INSIDE MAY PRESENT EXPLO HAZ.

Respiratory Protection:FOR VAPOR OR MIST EXPOSURE, WEAR NIOSH/MSHA
APPROVED FULL-FACE OR HALF-FACE AIR-PURIFYING RESPIRATOR APPROVED
FOR PESTICIDES. RESPIRATOR SELECTION IS BASED ON AIRBORNE
CONCENTRATION.
Ventilation:USE LOC EXHST @ ALL PROCESS LOCATIONS TO CTRL EMPLOYEE
EXPOS. THORO VENT ALL TRANSPORT VEHICLES PRIOR TO UNLOADING.
Protective Gloves:CHEMICAL PROTECTIVE GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYEWASH FOUNTAIN SHLD BE LOCATED NEARBY.
DEPENDING UPON CONC ENCOUNTERED, LONG-SLEEVED
UNIFORM/COVERALLS/HEAD COVERING.
Work Hygienic Practices:WASH EXPOSED SKIN SURF BEFORE
SMOKING/DRINKING/EATING. WORKERS SHLD SHOWER AT END OF EACH WORK
SHIFT. LAUNDER (ING 21)
Supplemental Safety and Health
FIRE FIGHT PROC:CNTNRS COOL W/SOFT STREAM H*2O FOG. EXPLO
HAZ:W/VIOLENCE >150C(302C). EFTS OF OVEREXP:EYES/NOSE/THROAT CAN
RSLT FROM INHAL EXPOS TO ONE INGRED. INHAL OF PETROLEUM DISTILLATE
CAN CAUSE RESP IRRIT/DISCOMFORT, INCL NASAL DISCHARGE, SORE
THROAT, COUGHING, BRONCHITIS, PULM EDEMA & DIFFICULTY BRTHG. (ING
4)

Vapor Pres:0.0000015
Spec Gravity:0.854 @ 20C
Solubility in Water:EMULSIFIES
Appearance and Odor:VISCOUS LIQUID, MERCAPTAN-LIKE ODOR.

Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:EXCESSIVE HEAT AND FIRE.
Hazardous Decomposition Products:THERMAL DECOMPOSITION AND BURNING MAY
PRODUCE TOXIC BY-PRODUCTS. CO, CO*2, PHENOLS, SULFUR OXIDES,
MERCAPTANS.

Waste Disposal Methods:OPEN DUMPING/BURNING OF MATL/IT PACKAGING IS
PROHIBITED. AN ACCEPTABLE METHOD OF DISP IS TO BURN IN AN
INCINERATOR I/A/W ALL LOC, STATE & FED ENVIRONMENTAL LAWS, RULES,
STANDARDS ®S. BECAUSE ACCEPT METHODS OF DISP MAY VARY BY
LOCATION, & (ING 24)

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